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Metals - Problems of Extraction
Recycling titanium would increase if more uses of titanium were found.

Metals - Problems of Extraction

In this GCSE Chemistry quiz, one in a series on the subject of metals, we look at some of the problems associated with the extraction of metals from their ores, such as the financial and the environmental costs.

Metallurgy is the science of metals and it has changed the way people live their lives. However, there are many issues involved with the extraction and processing of metals, from the initial removal of the ore from the ground to the production of the finished items. Some are purely environmental problems but others involve people too. For the GCSE, you need to be able to consider and evaluate the social, economic and environmental impacts of exploiting metal ores, of using metals and of recycling metals. But don't worry, much of it is common sense and some general knowledge. Several of the issues you learnt whilst studying the quarrying of limestone can be applied to mining.

Mining metal ores involves digging out and processing large quantities of rock. Many of these mines penetrate deep into the Earth but some are open - they are literally massive holes in which which huge machines are used to extract the ore. But what is an ore? Simply put, if a rock contains a high enough concentration of a metal to make it economically worth extracting, then it is an ore. The terms high grade and low grade are applied to ores. You can probably guess what these terms mean. Over time, the price that manufacturers will pay for a metal changes and it is possible that over time, the economics of ore extraction may also change, making it worthwhile to extract low grade ores.

One major environmental problem with mining ores is what to do with the spoil (waste material from the mining) as this contains traces of the ore which is often toxic. When it rains, traces of the metals can leach out. This leaching can spread the toxic waste more widely into the environment. An example of this is from lead mining in Derbyshire. Around the lead mines, which have not been worked for over a century, the only plants that grow on and near the spoil heaps are species that are not killed by lead and the other metals that were mined, like zinc and copper. However, this spoil has lead to some new mining methods being developed.

Phytomining is a method of extracting metals from low grade ore and spoil. Metal tolerant plants are deliberately grown on mining waste then harvested and a new crop planted. The harvested plants are treated and the metals extracted. This has many benefits - it reduces the levels of toxic metals in the environment, increases the quantity of metal extracted from a mine and increases the profit for the mining company. The disadvantages are that it is slow and relatively expensive as only small amounts of metal are produced. A similar method using bacteria has also been developed - bioleaching.

Issues surrounding the extraction of the metals from their ores are the use of energy and the production of carbon dioxide during the processing. In the blast furnace, there is a lot of CO2 produced, since carbon is used as the reducing agent. During the production of aluminium, the carbon anodes burn away in the oxygen that is produced during the electrolysis of the bauxite, producing carbon dioxide. It also uses vast quantities of electricity - producing that electricity will release carbon dioxide into the air too.

Another method of reducing the problems of metal extraction is to avoid it entirely by recycling metals. It is not possible to recycle everything so there will always be a need for mining and extraction of metals.

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1.
Some iron is obtained by recycling scrap iron. Why does it take less energy to make iron from scrap iron than to extract the iron from its ore?
Scrap iron does not have to be reduced using carbon
Scrap iron contains the element sulfur
Scrap iron is an alloy
Corrosion of the scrap iron makes it easier to melt
To extract iron from haematite requires iron to be heated with carbon. This uses huge amounts of energy and requires other resources to be mined (limestone and coal)
2.
If aluminium cans are not recycled, they can have a huge impact on the environment in which of the following ways?
They produce poisonous gases
They cause acid rain
They fill up landfill rubbish tips
They corrode rapidly in lakes and rivers
It is better to crush cans for recycling as it means that more can be transported in fewer journeys, saving more energy
3.
Scientists have been looking for alternative methods to extract copper from the ground. One of these methods is bioleaching. What does bioleaching use to extract copper?
Plants
Bacteria
Animals
Viruses
Bacteria live in the copper ore and break down the copper compounds. They produce acidic solutions which dissolve the copper compounds and these can be collected
4.
A disadvantage of extracting aluminium from aluminium ore is...
aluminium ore is a limited resource
aluminium ore contains very small amounts of aluminium
the aluminium obtained corrodes easily
the aluminium obtained has a high density
The deposits of aluminium ore are a finite resource, i.e. they will run out eventually
5.
Economically, it is more sensible to recycle aluminium, because extracting it from its ore...
uses much larger amounts of energy
is a relatively cheap process
employs more people
takes a long time
Electrolysis uses huge amounts of electrical energy. Generating this electricity has an effect on the environment as well as the extraction process
6.
Which of the following is a disadvantage of bioleaching rather than extracting copper by the traditional method?
Bioleaching is more economical
Bioleaching is slower
Bioleaching uses less energy
Bioleaching allows us to use low-grade ores
Bioleaching takes longer than traditional mining as you have to wait for the bacteria to 'do its thing'
7.
Removing metal ores from the ground usually involves mining. Which of the following is NOT an environmental impact of mining?
Loss of habitat
Increase in global warming
Damage to the ozone layer
Noise pollution
Mining does not release CFCs, which are the leading contributor to damage of the ozone layer
8.
It is better to recycle aluminium than to extract it from aluminium ore because...
aluminium ore produces only low grade aluminium
aluminium ore doesn't contain many impurities
mining for aluminium ore destroys the local environment
recycling of aluminium produces ‘smart’ aluminium alloys
Recycling won't bring back the area destroyed by the mining but it will slow down the amount of damage being done
9.
Most titanium is extracted from titanium oxide ore. The oxide is first converted to titanium chloride. The titanium chloride is then reacted with sodium. This method of extracting titanium is very expensive. Recycling titanium would increase if...
the cost of sodium were to fall
new high-grade deposits of titanium oxide were discovered
the cost of titanium were to fall
more uses of titanium were found
There would be more of an incentive to recycle
10.
Recycling metals is often thought of as a better way to provide more metals. Which of the following is NOT an advantage of recycling?
Destruction of habitats
Preserves natural resources
Decreases landfill space required
It is cheaper than extraction from the ore
Even with the costs of transport, recycling usually requires less energy than starting from an ore which requires a lot of treatment and transport before it can reach the same point as the metal being recycled
Author:  Kate Gardiner

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